Eu@C72: Computed Comparable Populations of Two Non-IPR Isomers

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Eu@C72: Computed Comparable Populations of Two Non-IPR Isomers.

Relative concentrations of six isomeric Eu@C 72 -one based on the IPR C 72 cage (i.e., obeying the isolated-pentagon rule, IPR), two cages with a pentagon-pentagon junction (symmetries C 2 and C 2 v ), a cage with one heptagon, a cage with two heptagons, and a cage with two pentagon-pentagon fusions-are DFT computed using the Gibbs energy in a broad temperature interval. It is shown that the tw...

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ژورنال

عنوان ژورنال: Molecules

سال: 2017

ISSN: 1420-3049

DOI: 10.3390/molecules22071053